Note: the last resonance form shouldn't have an H on it!
For Question 4: (a) IntA is a tert-butyl radical, and IntB is an isobutyl radical
(can't draw them here yet!)
Remaining parts would not be on the 2003 summer exam #1:
(b) You draw a line starting from the energy level of the starting material, going up
to the energy level of each intermediate IntA and IntB, giving two different
act. energies for the pathways A & B.
(c) WIll be on test #2, don't worry about this for now.
(d) There is no part (d)!
(e) The product from A, 2-chloro-2-methylpropane, is the most stable, because it
is at a position of lower energy on the right hand side of the diagram.
This is confirmed
if you do the calculations in (d). This product is also formed more quickly than the
other product (1-chloro-2-methylpropane).